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61.
Since Berry argued in 1976 that counterurbanization had replaced urbanization in the U.S., a debate has ensued as to whether the phenomenon also exists in Western Europe. Proponents of a developmental theory of counterurbanization contend that the phenomenon should be evident in countries which have achieved a very high level of socioeconomic development, including the Federal Republic of Germany (FRG). Most of the German and English language literature on the topic suggests the contrary for the FRG. Here urbanization and counterurbanization are restricted to specific geographic meanings, i.e., spatial agglomeration and deglomeration. Results from four interrelated tests show a trend toward counterurbanization evident as early as the 1960s in the post-war regional demographic data of the FRG.  相似文献   
62.
High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a 206Pb/238U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.  相似文献   
63.
The concentration of selected trace metals (Cu, Pb and Zn) in salt-marsh sediments from within the Erme Estuary have been measured in order to assess possible historical sources of pollution. The Erme Estuary, south Devon, UK is an Area of Outstanding Natural Beauty and has remained largely unaffected by industrialisation, although a number of small silver–lead mines were in operation in the 1800s. Five cores reveal comparable geochemical profiles. An increase of lead at 40 cm depth is observed, reaching maximum values of 427 ppm. Less distinct trends are revealed by zinc and copper, probably reflecting the lack of widespread mining for ores of these elements within the catchment and possible post-depositional mobility rendering the metal concentrations non-contemporaneous with the chemostratigraphy of lead. The geochemical analysis of the salt-marsh sediments provides a fairly robust chemostratigraphic scheme and the likely sources of mine waste can be pinpointed within the catchment. Based upon reference to the historical mining record of these mines chemostratigraphic dating of the sediments can be achieved in order to provide an estimate of salt-marsh accretion rates and sea-level rise.  相似文献   
64.
Snow and weather observations at Weissfluhjoch were initiated in 1936, when a research team set a snow stake and started digging snow pits on a plateau located at 2,540?m asl above Davos, Switzerland. This was the beginning of what is now the longest series of daily snow depth, new snow height and bi-monthly snow water equivalent measurements from a high-altitude research station. Our investigations reveal that the snow depth at Weissfluhjoch with regard to the evolution and inter-annual variability represents a good proxy for the entire Swiss Alps. In order to set the snow and weather observations from Weissfluhjoch in a broader context, this paper also shows some comparisons with measurements from five other high-altitude observatories in the European Alps. The results show a surprisingly uniform warming of 0.8°C during the last three decades at the six investigated mountain stations. The long-term snow measurements reveal no change in mid-winter, but decreasing trends (especially since the 1980s) for the solid precipitation ratio, snow fall, snow water equivalent and snow depth during the melt season due to a strong temperature increase of 2.5°C in the spring and summer months of the last three decades.  相似文献   
65.
Global environmental change leads to degradation of tropical forests in many countries. In response to this pressure, programs for payments for ecosystem services (PES) are developing and organizations are emerging which manage forests in order to supply ecosystem services, rather than only harvest timber. Typically such services are carbon sequestration, biodiversity conservation, pollination, and watershed protection. Public or private actors interested to invest in or donate money for the provisioning of such services are faced with the problem of choosing the appropriate organization supplying ecosystem services. The goal of this paper was to develop an assessment framework based on the balanced scorecard concept including drivers, impact, performance and context variables. Results of a survey of international market actors were used to determine assessment criteria and their weights. Putting the focus of this paper on drivers and impacts, we assessed Latin American organizations that “sell” ecosystem services from tropical forests in terms of their general management, marketing, forest management, client and stakeholder satisfaction, and forest ecosystem status. We found that supplying organizations vary widely with respect to their achievements in these areas. However, the variance of assessment results is influenced even more by the variance in weights the international market actors allocate to the assessment criteria. The insights of this study can contribute to the continuous improvement of management processes in supplying organizations and can support investors and donors in their decision-making with respect to organization supplying ecosystem services.  相似文献   
66.
Near-total depletions of ozone have been observed in the Arctic spring since the mid 1980s. The autocatalytic reaction cycles involving reactive halogens are now recognized to be of main importance for ozone depletion events in the polar boundary layer. We present sensitivity studies using the model MISTRA in the box-model mode on the influence of chemical species on these ozone depletion processes. In order to test the sensitivity of the chemistry under polar conditions, we compared base runs undergoing fluxes of either Br2, BrCl, or Cl2 to induce ozone depletions, with similar runs including a modification of the chemical conditions. The role of HCHO, H2O2, DMS, Cl2, C2H6, HONO, NO2, and RONO2 was investigated. Cases with elevated mixing ratios of HCHO, H2O2, DMS, Cl2, and HONO induced a shift in bromine speciation from Br / BrO to HOBr/HBr, while high mixing ratios of C2H6 induced a shift from HOBr/HBr to Br/BrO. The shifts from Br/BrO to HOBr/HBr accelerated the aerosol debromination, but also increased the total amount of deposited bromine at the surface (mainly via increased deposition of HOBr). For all NOy species studied (HONO, NO2, RONO2) the chemistry is characterized by an increased bromine deposition on snow reducing the amount of reactive bromine in the air. Ozone is less depleted under conditions of high mixing ratios of NOx. The production of HNO3 led to the acid displacement of HCl, and the release of chlorine out of salt aerosol (Cl2 or BrCl) increased.  相似文献   
67.
68.
Journal of Paleolimnology - The oxygen isotope composition (δ18O) of aquatic cellulose extracted from lake sediment cores has long been used to reconstruct past hydrological responses to...  相似文献   
69.
]The activities of 18 radionuclides in 4 samples from the Saint-Séverin meteorite have been measured after chemical separation. The results show that the DI sample from the D piece has been less irradiated than the samples B2, B3 and B4 from the B piece. This is based on activities of isotopes produced both by spallation as 26Al, 53Mn, 54Mn, 55Fe, 57Co and by thermal neutron capture as 59Ni and 60Co.Comparison of experimental values to calculated production rates suggests that the D piece was connected to the main body of the meteorite by a small surface, and that the DI sample in this piece was opposite to the main body of the meteorite.  相似文献   
70.
Gas‐Oil Gravity Drainage is to be enhanced by steam injection in a highly fractured, low permeability carbonate field in Oman. Following a successful pilot, field‐wide steam injection is being implemented, first of this type in the world. A dedicated monitoring program has been designed to track changes in the reservoir. Various observations are to be acquired, including, surface deformation, temperature measurements, microseismic, well logs, pressure and saturation measurements to monitor the reservoir. Because significant changes in the reservoir density are expected, time‐lapse gravimetry is also being considered. In this paper we investigate the feasibility of gravimetric monitoring of the thermally enhanced gravity drainage process at the carbonate field in Oman. For this purpose, forward gravity modelling is performed. Based on field groundwater measurements, the estimates of the hydrological signal are considered and it is investigated under what conditions the groundwater influences can be minimized. Using regularized inversion of synthetic gravity data, we analyse the achievable accuracy of heat‐front position estimates. In case of large groundwater variations at the field, the gravity observations can be significantly affected and, consequently, the accuracy of heat‐front monitoring can be deteriorated. We show that, by applying gravity corrections based on local observations of groundwater, the hydrological influences can to a large extent be reduced and the accuracy of estimates can be improved. We conclude that gravimetric monitoring of the heat‐front evolution has a great potential.  相似文献   
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